Rules FAQ:
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Placing a card in the discard pile does not trigger any "When/After a card is discarded" abilities (e.g. Crone of Vaes Dothrak, Tywin Lannister (LoCR) ).
- Note that there is an action window during the standing phase, before taxantion (see Chart). So if you saved gold for Now My Watch Begins, but Queenscrown didn't reveal any relevant characters, you can use it again the same turn after cards stand but before you lose gold.